Phrase Hound found 18 phrases and 2 compound words that contain rearrangements. The most common are listed below. Open rearrangements in the live search for definitions, filters, and the full list.
Phrases 18
- Brook rearrangementsplural of Brook rearrangement: A rearrangement name reaction in which an organosilyl group switches position with a hydroxyl proton over a carbon-to-oxygen covalent bond under the influence of a base, yielding a silyl ether.
- Cope rearrangementsplural of Cope rearrangement: The (normally reversible) thermal isomerization of a 1,5-diene to yield a more stable regioisomer
- Hofmann rearrangementsplural of Hofmann rearrangement: The organic reaction of a primary amide to a primary amine with one carbon atom less. It involves oxidation of the nitrogen followed by rearrangement of the carbonyl and nitrogen to give an isocyanate …
- Schmidt rearrangementsplural of Schmidt rearrangement: The reaction of a carbonyl group with an azide to form an amine or amide
- Wolff rearrangementsplural of Wolff rearrangement: A reaction in which an α-diazocarbonyl compound is converted into a ketene and then into a variety of other compounds
- Beckmann rearrangementsplural of Beckmann rearrangement: A rearrangement of an oxime functional group to substituted amides. It has also been successfully performed on haloimines and nitrones. Cyclic oximes and haloimines yield lactams.
- Stieglitz rearrangementsplural of Stieglitz rearrangement: A rearrangement reaction involving the 1,2-rearrangement of trityl amine derivatives to triaryl imines.
- Bamberger rearrangementsplural of Bamberger rearrangement: The chemical reaction of phenylhydroxylamines with strong aqueous acid, which will rearrange to give 4-aminophenols.
- allylic rearrangementsplural of allylic rearrangement: An organic reaction in which the double bond in an allyl chemical compound shifts to the next carbon atom, encountered in nucleophilic substitution.
- Curtius rearrangementsplural of Curtius rearrangement: The thermal decomposition of an acyl azide to an isocyanate with loss of nitrogen gas. The isocyanate then undergoes attack by a variety of nucleophiles such as water, alcohols and amines, to yield a …
- Claisen rearrangementsplural of Claisen rearrangement: A powerful carbon–carbon bond-forming chemical reaction, in which the heating of an allyl vinyl ether initiates a [3,3]-sigmatropic rearrangement to give a γ,δ-unsaturated carbonyl.
- di-pimethane rearrangementsplural of di-pimethane rearrangement: A photochemical reaction of a molecular entity comprising two p-systems, separated by a saturated carbon atom (a 1,4-diene or an allyl-substituted aromatic analog), to form an ene- (or aryl-) …
- Lossen rearrangementsplural of Lossen rearrangement: The conversion of a hydroxamate ester to an isocyanate, typically employing O-acyl, sulfonyl, or phosphoryl O-derivative.
- Newman-Kwart rearrangementsplural of Newman-Kwart rearrangement: A rearrangement reaction in which the aryl group of an O-aryl thiocarbamate migrates from the oxygen atom to the sulfur atom, forming an S-aryl thiocarbamate.
- pinacol rearrangementsplural of pinacol rearrangement: A class of rearrangement reaction in which a 1,2-diol is converted into a ketone; especially the case of the conversion of pinacol into pinacolone
- semipinacol rearrangementsplural of semipinacol rearrangement: A rearrangement involving a carbocation with a hydroxy group adjacent to the electron-deficient centre.
- Skattebøl rearrangementsplural of Skattebøl rearrangement: A reaction that converts a geminal dihalo cyclopropane to an allene using an organolithium base.
- Wagner-Meerwein rearrangementsplural of Wagner-Meerwein rearrangement: Any of a class of carbocation 1,2-rearrangement reactions in which a hydrogen, alkyl or aryl group migrates from one carbon to a neighbouring carbon.
Compound words 2
- microrearrangementsplural of microrearrangement: A very small rearrangement (typically of genetic material in a chromosome)
- photorearrangementsplural of photorearrangement: Any photoisomerization reaction that leads to changes in the arrangement of atoms in a molecule